questions about the Pennsylvania Petrochemicals Complex….have answers? or, even more questions?

ethane cracker natural gas liquids shell public liability company ethylene polymerization plastic resin Beaver County, Pennsylvania

I request your answers to my questions – for which I personally have no, or perhaps malformed, answers – about the Pennsylvania Petrochemicals Complex in Monaca, Pennsylvania.

David L. Passmore https://davidpassmore.net (Distinguished Professor, Emeritus, Penn State; Academic Visitor, University of Pittsburgh)
2022-04-21

I have many questions about the ethane cracker and pellet manufacturing operation at the Pennsylvania Petrochemicals Complex in Monaca, Pennsylvania, for which I do not have answers. Maybe you have answers for me. I am ignorant. Educate me, please! Share information with me using the Disqus comment form at the bottom of this posting. Contact me privately with your answers or insights through a direct message on Twitter @DLPPassmore or via email at .

Rendering of the Soon-To-Be-Completed Pennsylvania Petrochemicals Complex

Figure 1: Rendering of the Soon-To-Be-Completed Pennsylvania Petrochemicals Complex

But, first, a brief background statement about my simple, personal understanding of ethane cracking and pellet manufacturing at the Pennsylvania Petrochemicals Complex, an understanding that I encourage you to dispute and suggest that I update. Then, I offer my questions. Bored with the background already? Then, jump directly to the questions.

Brief Background

Natural Gas Liquids

Obtaining methane for energy production is a primary focus of natural gas extraction from Marcellus Shale and Utica shale formations in the northeastern U.S. Natural gas extracted in north central and northeast Pennsylvania is described as “dry” because it contains mostly methane. However. so-called “wet” gas produced in southwestern Pennsylvania contains methane, but also natural gas liquids (NGLs) such as ethane, propane, butane, isobutane, and pentane. These co-products1 of natural gas production, while costly to separate from the natural gas stream, have commercial value to add profitability to the extraction of wet gas.

Ethane Cracking

Historically, most NGLs used in the U.S. have been recovered from U.S. natural gas, although some have been sourced from crude oil refining and imports (Keller 2012). Ethane represents the highest proportion of NGLs in wet gas. Ethane distilled from natural gas liquids is a feedstock for ethylene production.

Ethylene is a raw material for the manufacture of polymers such as polyethylene, polyvinyl chloride, and polystyrene as well as fibers and other organic chemicals. A majority of ethylene is produced using a process called “steam cracking,” a thermal process in which hydrocarbons2 are broken down, or “cracked” into smaller molecules.

In a few words,3 superheated, pressurized steam causes ethane (C\(_{2}\)H\(_{6}\)) to vaporize, which splits the bonds between carbon and hydrogen atoms. Ethyelene molecules (H\(_{2}\)C⚌CH\(_{2}\)), form, freeing two hydrogen atoms. The resulting vapor is composed of ethylene, other hydrocarbons, unprocessed ethane molecules, and steam.4 The vapor undergoes additional processing to isolate the ethylene molecules.

Ethane Molecules are Cracked to Form Ethylene Molecules

Figure 2: Ethane Molecules are Cracked to Form Ethylene Molecules

Polymerization

Unique among elements is the capability of carbon to form single bonds chemically with up to four other atoms and to double bond with itself, as in an ethylene molecule. Carbon is one of the only elements, because of its bonding properties, that can create long chain-shaped molecules to form the basis for the fats, carbohydrates, nucleic acids (DNA and RNA), and proteins that serve as the basis of life itself. Chaining together ethylene molecules (monomers) through a chemical process called polymerization produces polyethylene (a polymer, which means “many parts”) with thermoplastic attributes. A thermoplastic has the property of softening or fusing when heated and of hardening and becoming rigid again when cooled.

Downstream Uses of Polyethylene

Polyethylene is the primary feedstock for manufacturing a vast range of consumer products, the foremost of which involve packaging (a few of many examples: sandwich wrap, cling wrap, moisture barriers, food packaging, box coating). Polyethylene often is produced as small pellets. These plastic pellets are unit-priced by the pound for sale in downstream markets. Pellet prices demonstrate volatility (Pederson 2021) because they are driven on the supply side by equally volatile prices for natural gas and on the demand side by consumer preferences for “eco-friendly” packaging solutions and by environmental regulation of plastic products.

Notable Inputs & By-Products of Ethane Cracking

Some Inputs

An ethane cracker gathers, usually through pipelines, a supply of ethane feedstock that has been fractionated [“Fractionation - an Overview | ScienceDirect Topics” (n.d.)]5 from the NGL spectrum in natural gas extracted from shale formations at well sites. Markedly, ethylene production uses a large amount of energy to superheat the steam that cracks ethylene from ethane.

Some By-Products

Cracking ethane emits hazardous by-products6 that can render the air, soil, water, or other natural resources harmful or unsuitable for use. Small inhalable particles (e.g., PM\(_{2.5}\)), another by-product of ethane production, can damage short- and long-term human respiratory function. Cracking also releases carbon dioxide (CO\(_{2}\)), a gas that can absorb energy within the infrared wavelengths. This energy is transferred by collision with other molecules. Faster molecular motion produces heat. Trapped heat from this action of carbon dioxide in the Earth’s atmosphere is the “greenhouse effect” that has affected global warming.

The Pennsylvania Petrochemical Complex

Shell7 made a final investment decision to build an ethane cracker integrated with a plastic pellet manufacturing facility at the Pennsylvania Petrochemicals Complex on the Ohio River in Monaca, Pennsylvania (“Pennsylvania Petrochemicals Complex,” n.d.). The plant (see Figure 3) is nearing is nearing completion and could starting operating in late 2022, according to Shell announcements reported in the popular press (Melinek 2021).8 Shell has estimated variously the deployment of between 400 to 600 jobs at the Complex.

Google Map of Location of Pennsylvania Petrochemicals Complex

Figure 3: Google Map of Location of Pennsylvania Petrochemicals Complex

Shell has indicated that the plant will produce 1.6 million tons of various grades of polyethylene pellets from 3.9 million barrels of ethane annually. The ethane cracker is geographically proximal to ethane sources in Pennsylvania, Ohio, and West Virginia involved with wet gas production and processing from Marcellus and Utica shale formations.9 More than 70% of North American polyethylene customers are within a 700-mile radius of plastic pellet production at the Pennsylvania Petrochemical Complex.

According to a biting 2020 analysis offered by the Institute for Energy Economics and Financial Analysis (Sanzillo and Hipple 2020), the Pennsylvania Petrochemical Complex faces prospects of low product prices, risk of oversupply of plastic resins, stiff competition from other producers, volatility in ethane feedstock markets, the possibility of low overall economic growth, and competition from recycled plastics materials. Concluded by the Institute is that the Complex “will open to market conditions that are more challenging than when the project was planned. The [C]omplex is likely to be less profitable than expected and face an extended period of financial distress.”

Some of My Questions….You Have Answers?

What Motivates My Questions?

As I wrote, I have many questions about the Pennsylvania Petrochemicals Complex. In particular, I remain largely ignorant of many of the deep, fundamental facts about the Complex. Perhaps, you feel this way, too.

I believe I have answers to some questions, which I will share for your scrutiny. Answers to many of my questions are extant, of course. I merely have not discovered them. You can help by informing me about accessible documents that provide answers. And, perhaps you have new and important questions that I have not considered. Poke your questions into the stream of thought in this blog about the Pennsylvania Petrochemicals Complex.

What Qualifies as Answers?

I seek answers that possess the following attributes:

  1. General answers are not informative about ethane cracking, natural gas production, or the plastics industry. Rather, the Pennsylvania Petrochemicals Complex remains the focus of all answers.
  2. Primary sources are desired, not secondary reports. Often-cited and -repeated story lines about energy topics can originate in social media postings, manifestos from opposing or supporting advocacy groups, releases from public relations groups representing clients, or public statements from energy-using or -producing firms themselves. These secondary sources of fact, intention, or opinion – sometimes abstracted from primary sources – might be wholly or partially true. Yet, a careful examiner desires more primary direct, accountable information. For instance, citation of a press release about the amount of CO\(_{2}\) a facility will emit is less desirable information than an official, legal filing with regulatory authorities about the amount and kind of pollutants a facility certifies that it expects to emit. However, secondary sources might contain the only hints available about operational and financial details and intentions. Non-disclosure and translucence in secondary sources about such matters as technology, intentions, unanticipated events, and financing, in fact, can support strategy of actors representing specific interests.
  3. Open access and transparency about answers are necessary. For example, a publicly-accessible summary of an otherwise inaccessible10 report is nothing more than information that remains inaccessible for critical review. Also, information that is not accessible and about which details are hidden, selectively screened, or incompetently reported makes kernel information unverifiable. The message plainly becomes no more than hearsay. As Stevie Wonder once sang in his 1972 composition Superstition, “When you believe in things that you don’t understand, then you suffer.”

In sum: I wish to study accessible, documentable, and clear answers to questions about the Pennsylvania Petrochemical Complex.

But, Wait, What Are My Questions?

Some answers to these questions are available to me already. Others are not. Some answers are buried in dry regulatory or technical reports. It is even possible that no evidence is available to answer other questions now or, perhaps, will be available in the future.

I will refine or extend this list of questions as I learn more about the Pennsylvania Petrochemicals Complex:

  1. Inputs to the complex
  1. Outputs from the complex
  1. Performance of the complex

And, Where Are Answers Documented?

I request that you share information with me about these and other useful questions or, better yet, provide answers to questions using the Disqus contact form at the bottom of this page. Contact me privately with your insights through a direct message on Twitter @DLPPassmore or via email at . Yes, you will be credited for your contribution.

In the next week (today is 21 April), I will open a posting in this blog site (served at davidpassmore.github.io/blog) that will contain questions asked and answers I have assembled to date. I will update this current paragraph to display the URL of the blog posting when it becomes available. Updates of the “Q & A” blog posting will occur as questions are refined or extended and when additional answers are provided. The blog posting will offer an RSS feed and a subscription link to allow notification about changes that occur in the posting.

[1] "2022-05-04 16:19:50 EDT"

Reuse

Text and figures are licensed under Creative Commons Attribution CC BY 4.0. Source code is available at https://github.com/davidpassmore/blog, unless otherwise noted. The figures that have been reused from other sources do not fall under this license and are recognized by footnoted text: “Figure from …”.

Comments/Corrections

To make comments about this posting or to suggest changes or corrections, send email to David Passmore, send a direct message on Twitter at @DLPPassmore, or send an IMsg or SMS to .

Callahan, David, Robert Brundrett, and Charlie Burd. 2022. “David Callahan, Robert Brundrett and Charlie Burd: Celebrating Appalachia’s Green Transformation.” https://triblive.com/opinion/david-callahan-robert-brundrett-and-charlie-burd-celebrating-appalachias-green-transformation/.
“Fractionation - an Overview | ScienceDirect Topics.” n.d. https://www.sciencedirect.com/topics/earth-and-planetary-sciences/fractionation.
Keller, Anne. 2012. “NGL 101 - The Basics.” https://www.scribd.com/document/321009084/eia-ngl-workshop-anne-keller-pdf.
Melinek, Jacquelyn. 2021. “Shell Pennsylvania Petchems Project 70.” https://www.spglobal.com/commodityinsights/en/market-insights/latest-news/petrochemicals/031221-shell-pennsylvania-petchems-project-70-complete-operational-in-2022-spokesman.
Passmore, David L. 2022. “NOTES FROM PITTSBURGH: Understanding Input-Output Modeling for Assessing Potential Economic Impact.” https://davidpassmore.github.io/blog/posts/2022-04-04-repoimplan/.
Pederson, Jacki. 2021. “Plastic Resin Prices 2021 | Resin Shortage & Cost of Plastic Explained.” https://summitpackaging.com/plastic-resin-prices-2021-resin-shortage/.
“Pennsylvania Petrochemicals Complex.” n.d. https://www.shell.com/about-us/major-projects/pennsylvania-petrochemicals-complex.html.
Sanzillo, Tom, and Kathy Hipple. 2020. “IEEFA Report: Financial Risks Loom for Shells Pennsylvania Petrochemicals Complex.” http://ieefa.org/ieefa-report-financial-risks-loom-for-shells-pennsylvania-petrochemical-complex/.
Shadish, William, Thomas Cook, and Donald Campbell. 2001. Experimental and Quasi-Experimental Designs for Generalized Causal Inference. Boston, Massachusetts: Cengage Learning.

  1. A co-product, a desirable secondary good that is generated during the manufacturing process and can be sold or reused profitably, is different than a by-product, a material of value that is produced as a residual of, or incidental to, the production process. In an accounting sense, co-products generate revenue; by-products are associated with costs.↩︎

  2. organic chemical compound composed exclusively of hydrogen and carbon atoms↩︎

  3. and skipping many steps in the chemical engineering of ethylene production from ethane.↩︎

  4. Figure from https://insights.globalspec.com/article/1490/natural-gas-for-export-process-fundamentals-for-engineers-part-1.↩︎

  5. Chemical separation by successive operations, each removing from a liquid some proportion of one of the substances. The operation may be one of precipitation, or more familiarly of distillation.↩︎

  6. Again, a by-product differs from a co-product. A co-products generates revenue; a by-product is associated with costs.↩︎

  7. a public liability company incorporated in the UK↩︎

  8. Figure from Google Maps image↩︎

  9. According to leaders of coalitions of natural gas producers in Pennsylvania, West Virginia, and Ohio, “Our three states produce roughly one-third of America’s natural gas, making Appalachia the third largest gas producer in the world — behind only the U.S. itself and Russia” (Callahan, Brundrett, and Burd 2022).↩︎

  10. i.e, behind a pay wall or restricted to limited distribution among advocates.↩︎

  11. The area or region from which the Complex draws its workers.↩︎

References

Citation

For attribution, please cite this work as

Passmore (2022, April 21). NOTES FROM PITTSBURGH: questions about the Pennsylvania Petrochemicals Complex....have answers? or, even more questions?. Retrieved from https://davidpassmore.github.io/blog/ec/2022-04-19-questions/

BibTeX citation

@misc{passmore2022questions,
  author = {Passmore, David L.},
  title = {NOTES FROM PITTSBURGH: questions about the Pennsylvania Petrochemicals Complex....have answers? or, even more questions?},
  url = {https://davidpassmore.github.io/blog/ec/2022-04-19-questions/},
  year = {2022}
}